I don't think I've ever seen either in a SMPS.
I've seen plenty of mosfets and zener diodes though.
There are many different types of SMPS regulators. The most common ones (at least the mains operated ones) are fairly complex to understand.
I would start by looking at a simple SMPS buck regulator. Understand that, then the various simple derivatives (boost, generating a negative rail) and then go on to other topologies.
Look
here and
here and
here.
Depending on how deep you want to understand, some may be more applicable than others.